A Simple and Convenient Method for Epoxidation of Olefins without Metal Catalysts

Abstract

An easy method for epoxidation of olefins usingbleach (sodium hypochlorite) and either a stoichiometric or catalytic amount of bromide ion has been developed. Without any transition metal catalyst a variety of non-activated olefins give epoxides in high yields and good selectivity at ambient conditions.

Description

An easy method for epoxidation of olefins usingbleach (sodium hypochlorite) and either a stoichiometric or catalytic amount of bromide ion has been developed. Without any transition metal catalyst a variety of non-activated olefins give epoxides in high yields and good selectivity at ambient conditions.

Keywords

epoxidation; epoxides; oxidation; sodium hypochlorite

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