Browsing by Author "N. O. Mahmoodi"
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Item DIRECT SYNTHESIS OF g-BUTYROLACTONES VIA g-PHENYL SUBSTITUTED BUTYRIC ACIDS MEDIATED BENZYL RADICAL CYCLIZATION(2012-11-19) N. O. Mahmoodi; M. JazayriSynthesis of several g-butyrolactones with aromatic substitution at carbon 5 from comparative g-aryl acids with 25–85% yield are covered. The straight oxidation in the presence of peroxydisulphate-copper(II)chloride system in aqueous medium was applied. The reaction is highly regioselective and leads exclusively to g-butyrolactone, through stable benzylic radical intermediateItem DIRECT SYNTHESIS OF g-BUTYROLACTONES VIA g-PHENYL SUBSTITUTED BUTYRIC ACIDS MEDIATED BENZYL RADICAL CYCLIZATION(2012-11-14) N. O. Mahmoodi; M. JazayriSynthesis of several g-butyrolactones with aromatic substitution at carbon 5 from comparative g-aryl acids with 25–85% yield are covered. The straight oxidation in the presence of peroxydisulphate-copper(II)chloride system in aqueous medium was applied. The reaction is highly regioselective and leads exclusively to g-butyrolactone, through stable benzylic radical intermediate
