Pentamethylcyclopentadienylrhodium and -iridium Halides. I. Synthesis and Properties'
| dc.contributor.author | J. W. Kang | |
| dc.contributor.author | K. Moseley | |
| dc.contributor.author | P. M. MaitW | |
| dc.date.accessioned | 2012-11-21T09:38:34Z | |
| dc.date.accessioned | 2025-02-17T13:59:11Z | |
| dc.date.available | 2012-11-21T09:38:34Z | |
| dc.date.issued | 2012-11-21 | |
| dc.description | Details of the reactions of hexamethyl(Dewar benzene), HMDB (hexamethylbicyclo[2.2.0]hexadiene) (l), and of 1 -(1-chloroethy1)pentamethylcyclopentadiene (4a) with RhCI3.3HrO and IrC13.5H20 to give the pentamethylcyclopentadienyl complexes, (C3Me3MC12)(29 ,a nd proposals for the mechanisms of these reactions are presented. The pentamethylcyclopentadienyl-metal bond in 5 is very strong, but reactions readily proceed at the halogens. Adducts of the type C3MesRhClsL (L = p-toluidine, pyridine, triphenylphosphine) are described as well as their reactions to form C3MesRhMenPPha3n d CSMe3RhMeIPPh3.T he synthesis of CSMeSIr(C0)i2s also | en_US |
| dc.description.abstract | Details of the reactions of hexamethyl(Dewar benzene), HMDB (hexamethylbicyclo[2.2.0]hexadiene) (l), and of 1 -(1-chloroethy1)pentamethylcyclopentadiene (4a) with RhCI3.3HrO and IrC13.5H20 to give the pentamethylcyclopentadienyl complexes, (C3Me3MC12)(29 ,a nd proposals for the mechanisms of these reactions are presented. The pentamethylcyclopentadienyl-metal bond in 5 is very strong, but reactions readily proceed at the halogens. Adducts of the type C3MesRhClsL (L = p-toluidine, pyridine, triphenylphosphine) are described as well as their reactions to form C3MesRhMenPPha3n d CSMe3RhMeIPPh3.T he synthesis of CSMeSIr(C0)i2s also | en_US |
| dc.identifier.uri | https://dl.ftveti.edu.et/handle/123456789/3829 | |
| dc.language.iso | en | en_US |
| dc.subject | Pentamethylcyclopentadienylrhodium and -iridium Halides. I. Synthesis and Properties' | en_US |
| dc.title | Pentamethylcyclopentadienylrhodium and -iridium Halides. I. Synthesis and Properties' | en_US |
| dc.type | Article | en_US |
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