High Selectivity in the Oxidation of Mandelic Acid Derivatives and in O-Methylation of Protocatechualdehyde: New Processes for Synthesis of Vanillin, iso-Vanillin, and Heliotropin

dc.contributor.authorHans-Rene´ Bjørsvik
dc.contributor.authorLucia Liguori
dc.contributor.authorFrancesco Minisci
dc.date.accessioned2012-11-20T12:56:58Z
dc.date.accessioned2025-02-17T14:02:04Z
dc.date.available2012-11-20T12:56:58Z
dc.date.issued2012-11-20
dc.descriptionNew synthetic procedures for vanillin, iso-vanillin, heliotropin, and protocatechualdehyde starting from catechol are described. The utilisation of statistical experimental design and multivariate modelling and the mechanistic interpretation of the acid and base catalysis in the condensation of catechol derivatives with glyoxylic acid and in the regiocontrolled methylation of protocatechualdehyde and of the Cu(II) salt catalysis in the oxidative decarboxylation of mandelic acid derivatives have allowed the development of new highly selective processesen_US
dc.description.abstractNew synthetic procedures for vanillin, iso-vanillin, heliotropin, and protocatechualdehyde starting from catechol are described. The utilisation of statistical experimental design and multivariate modelling and the mechanistic interpretation of the acid and base catalysis in the condensation of catechol derivatives with glyoxylic acid and in the regiocontrolled methylation of protocatechualdehyde and of the Cu(II) salt catalysis in the oxidative decarboxylation of mandelic acid derivatives have allowed the development of new highly selective processesen_US
dc.identifier.urihttps://dl.ftveti.edu.et/handle/123456789/4216
dc.language.isoenen_US
dc.subjectHigh Selectivity in the Oxidation of Mandelic Acid Derivatives and in O-Methylation of Protocatechualdehyde: New Processes for Synthesis of Vanillin, iso-Vanillin, and Heliotropinen_US
dc.titleHigh Selectivity in the Oxidation of Mandelic Acid Derivatives and in O-Methylation of Protocatechualdehyde: New Processes for Synthesis of Vanillin, iso-Vanillin, and Heliotropinen_US
dc.typeArticleen_US

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