Preparation of Nickel-on-Charcoal (Ni/C): An Improved Protocol

dc.contributor.authorBruce H. Lipshutz
dc.contributor.authorStefan Tasler
dc.date.accessioned2012-11-20T13:51:12Z
dc.date.accessioned2025-02-17T14:02:12Z
dc.date.available2012-11-20T13:51:12Z
dc.date.issued2012-11-20
dc.descriptionA modified preparation of the inexpensive, heterogeneous precatalyst Ni(II)/C, has been developed which (1) reduces the number of solvent distillations; (2) generates no organic waste; (3) leads to complete impregnation of the Ni(II) salts invested; and (4) extends the number of sources of charcoal which can be used to make the catalyst. Several carbon±carbon, as well as carbon±nitrogen and carbon±hydrogen bond-forming reactions have been run which compare Ni/C prepared via this new protocol with those formed using the original protocol. The results from each are virtually identicalen_US
dc.description.abstractA modified preparation of the inexpensive, heterogeneous precatalyst Ni(II)/C, has been developed which (1) reduces the number of solvent distillations; (2) generates no organic waste; (3) leads to complete impregnation of the Ni(II) salts invested; and (4) extends the number of sources of charcoal which can be used to make the catalyst. Several carbon±carbon, as well as carbon±nitrogen and carbon±hydrogen bond-forming reactions have been run which compare Ni/C prepared via this new protocol with those formed using the original protocol. The results from each are virtually identicalen_US
dc.identifier.urihttps://dl.ftveti.edu.et/handle/123456789/4234
dc.language.isoenen_US
dc.subjectaromatic aminations; aryl chlorides; biaryls; cross-couplings; heterogeneous catalysis; nickel-on-charcoalen_US
dc.titlePreparation of Nickel-on-Charcoal (Ni/C): An Improved Protocolen_US
dc.typeArticleen_US

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