Catalytic Leuckart-Wallach-Type Reductive Amination of Ketones
| dc.contributor.author | Masato Kitamura | |
| dc.contributor.author | Donghyun Lee | |
| dc.contributor.author | Shinnosuke Hayashi | |
| dc.contributor.author | Shinji Tanaka | |
| dc.contributor.author | Masahiro Yoshimura | |
| dc.date.accessioned | 2012-11-09T07:14:04Z | |
| dc.date.accessioned | 2025-02-17T13:59:32Z | |
| dc.date.available | 2012-11-09T07:14:04Z | |
| dc.date.issued | 2012-11-08 | |
| dc.description | Cp*Rh(III) complex catalyzes reductive amination of ketones using HCOONH4 at 50-70 °C to give the corresponding primary amines in high yields. The reaction is clean and operationally simple and proceeds at a lower temperature and with higher chemoselectivity than the original Leuckart-Wallach reaction. The new method has been applied to the synthesis of R-amino acids directly from R-keto acids. | en_US |
| dc.description.abstract | Cp*Rh(III) complex catalyzes reductive amination of ketones using HCOONH4 at 50-70 °C to give the corresponding primary amines in high yields. The reaction is clean and operationally simple and proceeds at a lower temperature and with higher chemoselectivity than the original Leuckart-Wallach reaction. The new method has been applied to the synthesis of R-amino acids directly from R-keto acids. | en_US |
| dc.identifier.uri | https://dl.ftveti.edu.et/handle/123456789/3959 | |
| dc.language.iso | en | en_US |
| dc.subject | Catalytic Leuckart-Wallach-Type Reductive Amination of Ketones | en_US |
| dc.title | Catalytic Leuckart-Wallach-Type Reductive Amination of Ketones | en_US |
| dc.type | Article | en_US |
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