Copper(I)-Induced Addition of Amines to Unactivated Nitriles: The First General One-Step Synthesis of A&y1 Amidines
Date
2012-11-14
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Cu(T,Kl ptvmotes the con&nsatton of acetonitrtle lo and benwnim’h lb with prtmary end secon&ny
amines tog into amidtnes Jo-/ under mild condtttons. in high to quantitative ytelak Stoichiometric f-on of
Cu&amidines complexes allows to control the degree of substitution of resulting amid&es
Description
Cu(T,Kl ptvmotes the con&nsatton of acetonitrtle lo and benwnim’h lb with prtmary end secon&ny
amines tog into amidtnes Jo-/ under mild condtttons. in high to quantitative ytelak Stoichiometric f-on of
Cu&amidines complexes allows to control the degree of substitution of resulting amid&es
Keywords
Amidines; nitriles; omines; copper(l&catalyzed co&ens&ton.