A facile and efficient method for the rearrangement of aryl-substituted epoxides to aldehydes and ketones using bismuth triflate
| dc.contributor.author | Kaushik A. Bhatia | |
| dc.contributor.author | Kyle J. Eash | |
| dc.contributor.author | Nicholas M. Leonard | |
| dc.contributor.author | Matthew C. Oswald | |
| dc.contributor.author | Ram S. Mohan | |
| dc.date.accessioned | 2012-11-15T07:44:48Z | |
| dc.date.accessioned | 2025-02-17T14:01:28Z | |
| dc.date.available | 2012-11-15T07:44:48Z | |
| dc.date.issued | 2012-11-14 | |
| dc.description | Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01–0.1 mol% Bi(OTf)3·xH2O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic C O bond. The highly catalytic nature of this method coupled with the fact that the reagent is relatively non-toxic, easy to handle and inexpensive make it an attractive alternative to more corrosive and toxic Lewis acids, such as BF3·Et2O, currently used to effect epoxide rearrangements. © 2001 Elsevier Science Ltd. All rights reserved. | en_US |
| dc.description.abstract | Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01–0.1 mol% Bi(OTf)3·xH2O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic C O bond. The highly catalytic nature of this method coupled with the fact that the reagent is relatively non-toxic, easy to handle and inexpensive make it an attractive alternative to more corrosive and toxic Lewis acids, such as BF3·Et2O, currently used to effect epoxide rearrangements. © 2001 Elsevier Science Ltd. All rights reserved. | en_US |
| dc.identifier.uri | https://dl.ftveti.edu.et/handle/123456789/4126 | |
| dc.language.iso | en | en_US |
| dc.subject | A facile and efficient method for the rearrangement of aryl-substituted epoxides to aldehydes and ketones using bismuth triflate | en_US |
| dc.title | A facile and efficient method for the rearrangement of aryl-substituted epoxides to aldehydes and ketones using bismuth triflate | en_US |
| dc.type | Article | en_US |
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